Handbook of Polymers for Pharmaceutical Technologies - Vol 1 (2015) Pdf Free Download

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Polymers and their derivative materials have been used most frequently as attractive alternatives to traditional medicinal materials for a number of pharmaceutical applications. For instance, polymeric matrices are the most widely employed system for preparation of controlled release pharmaceutical dosage forms due to their simple and low-cost manufacturing process. Th ere are three main types of pharmaceutical matrices: inert, hydrophilic and lipidic matrices, hydrophilic and inert matrices being the ones most employed. Different types of polymeric materials, namely ethylcellulose, polymethacrylates, polyvinyl acetate mixtures, cellulose ethers, hydroxypropylmethylcellulose, methylcellulose, sodium carboxymethylcellulose, chitosan, gums, xanthan gum, guar gum, polyethyleneoxide, sodium alginate and starch derivatives, to name but a few, have been used as materials for pharmaceutical matrices. Along with polymers, biomaterials with specific abilities to interact with biological structures have been widely used in the development of different devices intended for biomedical applications. Within this field, the interest in endogenous polymers as components of delivery systems has also gained increasing attention. Th e pharmaceutical role of polymers in the context of modern biomedical applications is increasing rapidly, such as in the form of macromolecular polymers to modify drug release. Th ere are a number of different macromolecular polymers that can be used to modify drug release from Extended release (ER) matrices. The ER oral dosage forms provide a number of therapeutic benefits (i.e., improved efficacy, reduced frequency of administration and better patient compliance) and retain market share. Due to the costs involved in discovering, developing and testing their safety, and getting approval for new polymeric materials, a new focus has been directed towards the investigation of the use of pharmaceutically approved polymer blends as matrix formers. Combining polymers of different chemistries or viscosities is being studied extensively as a means of achieving and optimizing extended drug release from hydrophilic matrices. Chemical conjugation with other pharmaceutical polymers such as poly(ethylene glycol) (PEG) has also evolved into a well-established technology used to improve the physicochemical, biomedical and pharmacological properties of several therapeutic molecules, such as peptides, proteins, antibodies, antibody fragments, oligonucleotides, and small drugs. Ubiquitously present nucleophillic groups, such as the terminal -NH2 group, the ε-NH2 group of lysine and the -SH group of cysteine, have all been used to couple peptides and proteins to mPEG derivatives. Moreover, site-selective, reversible and enzymatic PEGylation have recently gained increasing attention among the biopharmaceutical community.

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