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The developments in organic synthesis in recent years have been as dramatic as any that have occurred in laboratory sciences. The chemistry horizon has expanded and consolidated in such a way that one needs only mention a few terms to understand that chemical systems that did not exist roughly twenty years ago have now become a part of repertoire of synthetic organic chemistry pertaining to various research endeavours. The list of such terms would include the name reactions, organometallics, organocatalysis, oxidation, reduction, C–H activation, NHC, biocatalysis, etc. Surprisingly, the advances to the manipulations of these reaction techniques in a so called ‘‘nonhazardous/safer/greener’’ manner for the manufacturing of products of various interests have been unsuccessful in materializing a way forward for a sustainable world. The purpose of this book is to sensitize the chemistry fraternity to the idea that the usage of hazardous reagents in manufacturing of goods no longer fits in any business, environmental or technical propositions. It is rather mandatory or unavoidable to find alternates for all reported legendary yet hazardous reagents meant for or currently used for material production.

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